Kinetic Modeling of Three Textile Dyes Adsorption from Aqueous Solution onto a Cameroonian Smectite

Benessoubo Kada Daniele; Noubissié Eric; Yanne Etienne; Tekoumbo Tedontsa Larissa Canuala; Bike Mbah Jean Baptiste

doi:doi:10.11648/j.jeece.20210603.14

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Kinetic Modeling of Three Textile Dyes Adsorption from Aqueous Solution onto a Cameroonian Smectite

Benessoubo Kada Daniele, Noubissié Eric, Yanne Etienne, Tekoumbo Tedontsa Larissa Canuala, Bike Mbah Jean Baptiste

Published in Journal of Energy, Environmental & Chemical Engineering (Volume 6, Issue 3)

Received: 30 June 2021 Accepted: 19 July 2021 Published: 27 July 2021

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Abstract

In the present study, a Cameroonian smectite was used as an adsorbent to model the adsorption kinetics of three textile dyes (malachite green, methyl red and acid blue 74) from aqueous solution in a batch system. The effects of pH and temperature were evaluated on the adsorption capacities, the times required to reach adsorption equilibrium and the adsorption mechanisms involved. It can be seen that, although the times required to reach the adsorption equilibrium are independent of the pH of the medium, the adsorption process studied is favourable in acidic media and is globally independent of temperature. Among the pseudo-ﬁrst and pseudo-second-order kinetic models used to analyse the experimental data, the pseudo-second-order model was the best suited to describe the adsorption of the three dyes onto the clay. The mechanism involved, independently of the dye, is therefore a two-step process: the transfer of dye molecules from the solution to the clay surface followed by the interaction between the molecules and the surface. The low value of activation energies indicates that the adsorption of Methyl red, Malachite green and Acid blue 74 on the studied clay is a physisorption process.

Published in	Journal of Energy, Environmental & Chemical Engineering (Volume 6, Issue 3)
DOI	10.11648/j.jeece.20210603.14
Page(s)	71-75
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Adsorption, Kinetic Modeling, Textile Dye, Cameroonian Smectite

References

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[7]	Santhy K. and Selvapathy P. (2006). Removal of reactive dyes from wastewater by adsorption on coir pith activated carbon. Bioresource Technology, 97, 1329-1336.
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[9]	Al-Gaashani R, Almasri D, Shomar B., Kochkodan V., 2021. Preparation and properties of novel activated carbon doped with aluminum oxide and silver for water treatment. Journal of Alloys and Compounds 858, 158372.
[10]	Zümriye A., 2001. Biosorption of reactive dyes by dried activated sluge: equilibrium and kinetic modeling. Biochemical Engineering Journal. Vol 7, p. 79-84.
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[12]	Obijole A. O, Mugera G. W, Mudzielwana R, Ndungu P. G, Samie A, Babatunde A. W, 2021. Hydrothermally treated aluminosilicate clay (HTAC) for remediation of fluoride and pathogens from water: Adsorbent characterization and adsorption modelling. Water Resources and Industry.
[13]	Bike Mbah J. B, Benessoubo K. D, Eko M. C, Tekoumbo T. L. C, Elimbi A, Kamga R, (2020). Adsorption mechanisms of pigments and free fatty acids in the discoloration of shea butter and palm oil by an acid-activated Cameroonian smectite. Scientific African 9, e00498.
[14]	Nguetnkam J. P., R. Kamga, F. Villiéras, G. E. Ekodeck, and, J. Yvon (2007). Pedogenic formation of smectites in a vertisol developed from granitic rock from Laélé (Cameroon, Central Africa). Clay Miner., 42, 523-537.
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APA Style

Benessoubo Kada Daniele, Noubissié Eric, Yanne Etienne, Tekoumbo Tedontsa Larissa Canuala, Bike Mbah Jean Baptiste. (2021). Kinetic Modeling of Three Textile Dyes Adsorption from Aqueous Solution onto a Cameroonian Smectite. Journal of Energy, Environmental & Chemical Engineering, 6(3), 71-75. https://doi.org/10.11648/j.jeece.20210603.14

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ACS Style

Benessoubo Kada Daniele; Noubissié Eric; Yanne Etienne; Tekoumbo Tedontsa Larissa Canuala; Bike Mbah Jean Baptiste. Kinetic Modeling of Three Textile Dyes Adsorption from Aqueous Solution onto a Cameroonian Smectite. J. Energy Environ. Chem. Eng. 2021, 6(3), 71-75. doi: 10.11648/j.jeece.20210603.14

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AMA Style

Benessoubo Kada Daniele, Noubissié Eric, Yanne Etienne, Tekoumbo Tedontsa Larissa Canuala, Bike Mbah Jean Baptiste. Kinetic Modeling of Three Textile Dyes Adsorption from Aqueous Solution onto a Cameroonian Smectite. J Energy Environ Chem Eng. 2021;6(3):71-75. doi: 10.11648/j.jeece.20210603.14

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@article{10.11648/j.jeece.20210603.14,
  author = {Benessoubo Kada Daniele and Noubissié Eric and Yanne Etienne and Tekoumbo Tedontsa Larissa Canuala and Bike Mbah Jean Baptiste},
  title = {Kinetic Modeling of Three Textile Dyes Adsorption from Aqueous Solution onto a Cameroonian Smectite},
  journal = {Journal of Energy, Environmental & Chemical Engineering},
  volume = {6},
  number = {3},
  pages = {71-75},
  doi = {10.11648/j.jeece.20210603.14},
  url = {https://doi.org/10.11648/j.jeece.20210603.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jeece.20210603.14},
  abstract = {In the present study, a Cameroonian smectite was used as an adsorbent to model the adsorption kinetics of three textile dyes (malachite green, methyl red and acid blue 74) from aqueous solution in a batch system. The effects of pH and temperature were evaluated on the adsorption capacities, the times required to reach adsorption equilibrium and the adsorption mechanisms involved. It can be seen that, although the times required to reach the adsorption equilibrium are independent of the pH of the medium, the adsorption process studied is favourable in acidic media and is globally independent of temperature. Among the pseudo-ﬁrst and pseudo-second-order kinetic models used to analyse the experimental data, the pseudo-second-order model was the best suited to describe the adsorption of the three dyes onto the clay. The mechanism involved, independently of the dye, is therefore a two-step process: the transfer of dye molecules from the solution to the clay surface followed by the interaction between the molecules and the surface. The low value of activation energies indicates that the adsorption of Methyl red, Malachite green and Acid blue 74 on the studied clay is a physisorption process.},
 year = {2021}
}

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TY  - JOUR
T1  - Kinetic Modeling of Three Textile Dyes Adsorption from Aqueous Solution onto a Cameroonian Smectite
AU  - Benessoubo Kada Daniele
AU  - Noubissié Eric
AU  - Yanne Etienne
AU  - Tekoumbo Tedontsa Larissa Canuala
AU  - Bike Mbah Jean Baptiste
Y1  - 2021/07/27
PY  - 2021
N1  - https://doi.org/10.11648/j.jeece.20210603.14
DO  - 10.11648/j.jeece.20210603.14
T2  - Journal of Energy, Environmental & Chemical Engineering
JF  - Journal of Energy, Environmental & Chemical Engineering
JO  - Journal of Energy, Environmental & Chemical Engineering
SP  - 71
EP  - 75
PB  - Science Publishing Group
SN  - 2637-434X
UR  - https://doi.org/10.11648/j.jeece.20210603.14
AB  - In the present study, a Cameroonian smectite was used as an adsorbent to model the adsorption kinetics of three textile dyes (malachite green, methyl red and acid blue 74) from aqueous solution in a batch system. The effects of pH and temperature were evaluated on the adsorption capacities, the times required to reach adsorption equilibrium and the adsorption mechanisms involved. It can be seen that, although the times required to reach the adsorption equilibrium are independent of the pH of the medium, the adsorption process studied is favourable in acidic media and is globally independent of temperature. Among the pseudo-ﬁrst and pseudo-second-order kinetic models used to analyse the experimental data, the pseudo-second-order model was the best suited to describe the adsorption of the three dyes onto the clay. The mechanism involved, independently of the dye, is therefore a two-step process: the transfer of dye molecules from the solution to the clay surface followed by the interaction between the molecules and the surface. The low value of activation energies indicates that the adsorption of Methyl red, Malachite green and Acid blue 74 on the studied clay is a physisorption process.
VL  - 6
IS  - 3
ER  -

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Author Information

Benessoubo Kada Daniele

National School of Agro-Industrial Sciences, University of Ngaoundere, Ngaoundere, Cameroun
Noubissié Eric

University Institute of Technology, University of Ngaoundere, Ngaoundere, Cameroun
Yanne Etienne

National Polytechnic School, University of Maroua, Maroua, Cameroon
Tekoumbo Tedontsa Larissa Canuala

National School of Agro-Industrial Sciences, University of Ngaoundere, Ngaoundere, Cameroun
Bike Mbah Jean Baptiste

National School of Agro-Industrial Sciences, University of Ngaoundere, Ngaoundere, Cameroun

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APA Style

Benessoubo Kada Daniele, Noubissié Eric, Yanne Etienne, Tekoumbo Tedontsa Larissa Canuala, Bike Mbah Jean Baptiste. (2021). Kinetic Modeling of Three Textile Dyes Adsorption from Aqueous Solution onto a Cameroonian Smectite. Journal of Energy, Environmental & Chemical Engineering, 6(3), 71-75. https://doi.org/10.11648/j.jeece.20210603.14

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ACS Style

Benessoubo Kada Daniele; Noubissié Eric; Yanne Etienne; Tekoumbo Tedontsa Larissa Canuala; Bike Mbah Jean Baptiste. Kinetic Modeling of Three Textile Dyes Adsorption from Aqueous Solution onto a Cameroonian Smectite. J. Energy Environ. Chem. Eng. 2021, 6(3), 71-75. doi: 10.11648/j.jeece.20210603.14

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AMA Style

Benessoubo Kada Daniele, Noubissié Eric, Yanne Etienne, Tekoumbo Tedontsa Larissa Canuala, Bike Mbah Jean Baptiste. Kinetic Modeling of Three Textile Dyes Adsorption from Aqueous Solution onto a Cameroonian Smectite. J Energy Environ Chem Eng. 2021;6(3):71-75. doi: 10.11648/j.jeece.20210603.14

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@article{10.11648/j.jeece.20210603.14,
  author = {Benessoubo Kada Daniele and Noubissié Eric and Yanne Etienne and Tekoumbo Tedontsa Larissa Canuala and Bike Mbah Jean Baptiste},
  title = {Kinetic Modeling of Three Textile Dyes Adsorption from Aqueous Solution onto a Cameroonian Smectite},
  journal = {Journal of Energy, Environmental & Chemical Engineering},
  volume = {6},
  number = {3},
  pages = {71-75},
  doi = {10.11648/j.jeece.20210603.14},
  url = {https://doi.org/10.11648/j.jeece.20210603.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jeece.20210603.14},
  abstract = {In the present study, a Cameroonian smectite was used as an adsorbent to model the adsorption kinetics of three textile dyes (malachite green, methyl red and acid blue 74) from aqueous solution in a batch system. The effects of pH and temperature were evaluated on the adsorption capacities, the times required to reach adsorption equilibrium and the adsorption mechanisms involved. It can be seen that, although the times required to reach the adsorption equilibrium are independent of the pH of the medium, the adsorption process studied is favourable in acidic media and is globally independent of temperature. Among the pseudo-ﬁrst and pseudo-second-order kinetic models used to analyse the experimental data, the pseudo-second-order model was the best suited to describe the adsorption of the three dyes onto the clay. The mechanism involved, independently of the dye, is therefore a two-step process: the transfer of dye molecules from the solution to the clay surface followed by the interaction between the molecules and the surface. The low value of activation energies indicates that the adsorption of Methyl red, Malachite green and Acid blue 74 on the studied clay is a physisorption process.},
 year = {2021}
}

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TY  - JOUR
T1  - Kinetic Modeling of Three Textile Dyes Adsorption from Aqueous Solution onto a Cameroonian Smectite
AU  - Benessoubo Kada Daniele
AU  - Noubissié Eric
AU  - Yanne Etienne
AU  - Tekoumbo Tedontsa Larissa Canuala
AU  - Bike Mbah Jean Baptiste
Y1  - 2021/07/27
PY  - 2021
N1  - https://doi.org/10.11648/j.jeece.20210603.14
DO  - 10.11648/j.jeece.20210603.14
T2  - Journal of Energy, Environmental & Chemical Engineering
JF  - Journal of Energy, Environmental & Chemical Engineering
JO  - Journal of Energy, Environmental & Chemical Engineering
SP  - 71
EP  - 75
PB  - Science Publishing Group
SN  - 2637-434X
UR  - https://doi.org/10.11648/j.jeece.20210603.14
AB  - In the present study, a Cameroonian smectite was used as an adsorbent to model the adsorption kinetics of three textile dyes (malachite green, methyl red and acid blue 74) from aqueous solution in a batch system. The effects of pH and temperature were evaluated on the adsorption capacities, the times required to reach adsorption equilibrium and the adsorption mechanisms involved. It can be seen that, although the times required to reach the adsorption equilibrium are independent of the pH of the medium, the adsorption process studied is favourable in acidic media and is globally independent of temperature. Among the pseudo-ﬁrst and pseudo-second-order kinetic models used to analyse the experimental data, the pseudo-second-order model was the best suited to describe the adsorption of the three dyes onto the clay. The mechanism involved, independently of the dye, is therefore a two-step process: the transfer of dye molecules from the solution to the clay surface followed by the interaction between the molecules and the surface. The low value of activation energies indicates that the adsorption of Methyl red, Malachite green and Acid blue 74 on the studied clay is a physisorption process.
VL  - 6
IS  - 3
ER  -

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