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Adsorption, Kinetic and Thermodynamic Studies for Mercury Extraction from Water Samples Using Mesoporous Silica

Received: Aug. 15, 2019    Accepted: Sep. 09, 2019    Published: Sep. 29, 2019
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Abstract

Mercury is recognized internationally as an important pollutant since mercury and its compounds are persistent, bioaccumulative and toxic, and pose human and ecosystem risks. A critical aspect of mercury cycling is its bioaccumulation, mainly as methylmercury, along the contaminated water with mercury resulting in high risk of human. Adsorption of mercury from water samples on mesoporous silica, mercaptopropyl functionalysed-SBA-15 (MP-SBA-15) and diethylenetriamine functionalysed-SBA-15 (DETA-SBA-15) has been studied. SBA-15 was prepared by using Pluronic P123, PEO20PPO70PEO20 and tetraethylorthosilicate. Surface modification of SBA-15 was carried out by MP-TMS or DETA-TMS to produce MP-SBA-15 or DETA-SBA-15, respectively. SBA-15 and functionalised SBA-15 materials were characterised for BET surface area, pore size and pore volume. The adsorption kinetics and adsorption isotherms of functionalised SBA-15 for mercury were investigated. Results revealed that the adsorption kinetics were fitted by a pseudo-second-order reaction model and the adsorption thermodynamic parameters ΔH°, ΔS° and ΔE° were 42.08 kJ/mol, 210.3 J/mol.K and 7.20 kJ/mol, respectively for DETA-SBA-15; 101.85 kJ/mol, 397.7 J/mol.K and 23.28 kJ/mol, respectively for MP-SBA-15. Langmuir and Freundlich isotherm models were also applied to analyse the experimental data and to predict the relevant isotherm parameters. The best interpretation for the experimental data was given by the Langmuir isotherm equation. The results indicate that the structure of the materials affects the adsorption behavior. These materials show a potential for the application as effective and selective adsorbents for Hg(II) removal from water.

DOI 10.11648/j.mc.20190703.13
Published in Modern Chemistry ( Volume 7, Issue 3, September 2019 )
Page(s) 58-64
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Mercury Sorption, Mesoporous Silica, Sorption Kinetics, Sorption Thermodynamic, Equilibrium Isotherms

References
[1] L. A. Belyakova, O. M. Shvets, D. Y. e. Lyashenko, Inorganica Chimica Acta, 362 (2009) 2222-2230.
[2] I. M. M. Kenawy, Y. G. Abou El-Reash, M. M. Hassanien, N. R. Alnagar, W. I. Mortada, Microporous and Mesoporous Materials, 258 (2018) 217-227.
[3] J. Lu, X. Wu, Y. Li, W. Cui, Y. Liang, Surfaces and Interfaces, 12 (2018) 108-115.
[4] Y. Fu, J. Jiang, Z. Chen, S. Ying, J. Wang, J. Hu, Journal of Molecular Liquids, 286 (2019) 110746.
[5] USEPA, National Primary DrinkingWater Standards, Report EPA/625/R-97/004, in, Washington DC, 2001.
[6] J. Takahashi, K. Watanuki, S. Kubota, O. Wada, Y. Arikawa, S. Naito, S. Monma, T. Hirato, An Encyclopedia of Water, in, Maruzen Publishing Co., Tokyo, 2001.
[7] C. Foster, J. Wase, Biosorbents for Metal Ions, Taylor & Francis, New York, 1997.
[8] Y. Fu, Y. Sun, Z. Chen, S. Ying, J. Wang, J. Hu, Science of The Total Environment, 691 (2019) 664-674.
[9] A. A. Khan, Inamuddin, Sensors and Actuators B: Chemical, 120 (2006) 10-18.
[10] Z. Li, Q. Wei, R. Yuan, X. Zhou, H. Liu, H. Shan, Q. Song, Talanta, 71 (2007) 68-72.
[11] X. Lu, J. Jiang, K. Sun, J. Wang, Y. Zhang, Marine Pollution Bulletin, 78 (2014) 69-76.
[12] J. Zhou, X. Feng, H. Liu, H. Zhang, X. Fu, Z. Bao, X. Wang, Y. Zhang, Atmospheric Environment, 81 (2013) 364-372.
[13] K. Chakrabarty, P. Saha, A. K. Ghoshal, Journal of Membrane Science, 350 (2010) 395-401.
[14] S. A. Idris, S. R. Harvey, L. T. Gibson, Journal of Hazardous Materials, 193 (2011) 171-176.
[15] M. Shafiabadi, A. Dashti, H.-A. Tayebi, Synthetic Metals, 212 (2016) 154-160.
[16] S. A. Idris, C. Robertson, M. A. Morris, L. T. Gibson, Analytical Methods, 2 (2010) 1803-1809.
[17] I. Langmuir, J. Am. Chem. Soc., 40 (1918) 1361-1403.
[18] J.-u.-R. Memon, S. Q. Memon, M. I. Bhanger, M. Y. Khuhawar, J. Hazard. Mater., 163 (2009) 511-516.
[19] G. Purna Chandra Rao, S. Satyaveni, A. Ramesh, K. Seshaiah, K. S. N. Murthy, N. V. Choudary, Journal of Environmental Management, 81 (2006) 265-272.
[20] G. Zolfaghari, A. Esmaili-Sari, M. Anbia, H. Younesi, S. Amirmahmoodi, A. Ghafari-Nazari, Journal of Hazardous Materials, 192 (2011) 1046-1055.
[21] T. Y. Guo, Y. Q. Xia, G. J. Hao, M. D. Song, B. H. Zhang, Biomaterials, 25 (2004) 5905-5912.
[22] J. Pan, X. Zou, X. Wang, W. Guan, Y. Yan, J. Han, Chem. Eng. J. (Lausanne), 162 (2010) 910-918.
[23] S. Lagergren, Handlingar, 24 (1898) 1-39.
[24] Y. Ho, G. McKay, D. Wase, C. Foster, Adsorption Science and Technology 18 (2000) 639-650.
[25] S. Srivastava, R. Tygir, N. Pant, Water Res., 23 (1989) 1161-1165.
[26] W. Weber, J. Morris, Am. Soc. Civ. Eng., 89 (1963) 31-60.
[27] T. Wajima, K. Sugawara, Fuel Processing Technology, 92 (2011) 1322-1327.
[28] D. Pérez-Quintanilla, I. d. Hierro, M. Fajardo, I. Sierra, J. Hazard. Mater., 134 (2006) 245-256.
[29] J. Coates, Interpretation of Infrared Spectra, A Practical Approach, in: Encyclopedia of Analytical Chemistry, John Wiley & Sons, Ltd, 2006.
[30] Y.-S. Ho, W.-T. Chiu, C.-S. Hsu, C.-T. Huang, Hydrometallurgy, 73 (2004) 55-61.
[31] Y.-S. Ho, Water Research, 37 (2003) 2323-2330.
[32] S. Hong, C. Wen, J. He, F. Gan, Y.-S. Ho, Journal of Hazardous Materials, 167 (2009) 630-633.
[33] Y. Sağ, Y. Aktay, Process Biochemistry, 36 (2001) 1187-1197.
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    Salah Ali Mahgoub Idris. (2019). Adsorption, Kinetic and Thermodynamic Studies for Mercury Extraction from Water Samples Using Mesoporous Silica. Modern Chemistry, 7(3), 58-64. https://doi.org/10.11648/j.mc.20190703.13

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    ACS Style

    Salah Ali Mahgoub Idris. Adsorption, Kinetic and Thermodynamic Studies for Mercury Extraction from Water Samples Using Mesoporous Silica. Mod. Chem. 2019, 7(3), 58-64. doi: 10.11648/j.mc.20190703.13

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    AMA Style

    Salah Ali Mahgoub Idris. Adsorption, Kinetic and Thermodynamic Studies for Mercury Extraction from Water Samples Using Mesoporous Silica. Mod Chem. 2019;7(3):58-64. doi: 10.11648/j.mc.20190703.13

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  • @article{10.11648/j.mc.20190703.13,
      author = {Salah Ali Mahgoub Idris},
      title = {Adsorption, Kinetic and Thermodynamic Studies for Mercury Extraction from Water Samples Using Mesoporous Silica},
      journal = {Modern Chemistry},
      volume = {7},
      number = {3},
      pages = {58-64},
      doi = {10.11648/j.mc.20190703.13},
      url = {https://doi.org/10.11648/j.mc.20190703.13},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.mc.20190703.13},
      abstract = {Mercury is recognized internationally as an important pollutant since mercury and its compounds are persistent, bioaccumulative and toxic, and pose human and ecosystem risks. A critical aspect of mercury cycling is its bioaccumulation, mainly as methylmercury, along the contaminated water with mercury resulting in high risk of human. Adsorption of mercury from water samples on mesoporous silica, mercaptopropyl functionalysed-SBA-15 (MP-SBA-15) and diethylenetriamine functionalysed-SBA-15 (DETA-SBA-15) has been studied. SBA-15 was prepared by using Pluronic P123, PEO20PPO70PEO20 and tetraethylorthosilicate. Surface modification of SBA-15 was carried out by MP-TMS or DETA-TMS to produce MP-SBA-15 or DETA-SBA-15, respectively. SBA-15 and functionalised SBA-15 materials were characterised for BET surface area, pore size and pore volume. The adsorption kinetics and adsorption isotherms of functionalised SBA-15 for mercury were investigated. Results revealed that the adsorption kinetics were fitted by a pseudo-second-order reaction model and the adsorption thermodynamic parameters ΔH°, ΔS° and ΔE° were 42.08 kJ/mol, 210.3 J/mol.K and 7.20 kJ/mol, respectively for DETA-SBA-15; 101.85 kJ/mol, 397.7 J/mol.K and 23.28 kJ/mol, respectively for MP-SBA-15. Langmuir and Freundlich isotherm models were also applied to analyse the experimental data and to predict the relevant isotherm parameters. The best interpretation for the experimental data was given by the Langmuir isotherm equation. The results indicate that the structure of the materials affects the adsorption behavior. These materials show a potential for the application as effective and selective adsorbents for Hg(II) removal from water.},
     year = {2019}
    }
    

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  • TY  - JOUR
    T1  - Adsorption, Kinetic and Thermodynamic Studies for Mercury Extraction from Water Samples Using Mesoporous Silica
    AU  - Salah Ali Mahgoub Idris
    Y1  - 2019/09/29
    PY  - 2019
    N1  - https://doi.org/10.11648/j.mc.20190703.13
    DO  - 10.11648/j.mc.20190703.13
    T2  - Modern Chemistry
    JF  - Modern Chemistry
    JO  - Modern Chemistry
    SP  - 58
    EP  - 64
    PB  - Science Publishing Group
    SN  - 2329-180X
    UR  - https://doi.org/10.11648/j.mc.20190703.13
    AB  - Mercury is recognized internationally as an important pollutant since mercury and its compounds are persistent, bioaccumulative and toxic, and pose human and ecosystem risks. A critical aspect of mercury cycling is its bioaccumulation, mainly as methylmercury, along the contaminated water with mercury resulting in high risk of human. Adsorption of mercury from water samples on mesoporous silica, mercaptopropyl functionalysed-SBA-15 (MP-SBA-15) and diethylenetriamine functionalysed-SBA-15 (DETA-SBA-15) has been studied. SBA-15 was prepared by using Pluronic P123, PEO20PPO70PEO20 and tetraethylorthosilicate. Surface modification of SBA-15 was carried out by MP-TMS or DETA-TMS to produce MP-SBA-15 or DETA-SBA-15, respectively. SBA-15 and functionalised SBA-15 materials were characterised for BET surface area, pore size and pore volume. The adsorption kinetics and adsorption isotherms of functionalised SBA-15 for mercury were investigated. Results revealed that the adsorption kinetics were fitted by a pseudo-second-order reaction model and the adsorption thermodynamic parameters ΔH°, ΔS° and ΔE° were 42.08 kJ/mol, 210.3 J/mol.K and 7.20 kJ/mol, respectively for DETA-SBA-15; 101.85 kJ/mol, 397.7 J/mol.K and 23.28 kJ/mol, respectively for MP-SBA-15. Langmuir and Freundlich isotherm models were also applied to analyse the experimental data and to predict the relevant isotherm parameters. The best interpretation for the experimental data was given by the Langmuir isotherm equation. The results indicate that the structure of the materials affects the adsorption behavior. These materials show a potential for the application as effective and selective adsorbents for Hg(II) removal from water.
    VL  - 7
    IS  - 3
    ER  - 

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Author Information
  • Chemistry Department, Faculty of Science, University of Tobruk, Tobruk, Libya

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