Advances in Materials

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Environmentally Benign All-inorganic Perovskite Solar Cells

Received: Sep. 19, 2019    Accepted: Sep. 29, 2019    Published: Oct. 14, 2019
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Abstract

Organic/inorganic hybrid lead halide perovskite solar cells have recently emerged as the forerunner in the next generation of photovoltaic technology due to unprecedented progress in power conversion efficiency from their debut of 3.8% in 2009 to the currently certified 23.3%. Mixed PSC solar cells are subject to compositional degradation when exposed to ambient surroundings, which thwarts their real-world applications. Moreover, lead-based compounds pose environmental/health hazards. Very recently, all-inorganic lead-free perovskites have attracted enormous attention because this type successfully dismantles two roadblocks—instability and toxicity, which would accelerate the commercialization. In this outlook, we offered our perspective on the most recent developments in material sciences of halides all inorganic perovskites with possible alternatives to lead, the synthesis approaches, assessment of various device configurations and their progress in solar cells. For the sake of comparison, we also reviewed some all-inorganic but lead-based counterparts in order to motivate researchers to explore all the potentials. Surveying recent developments toward lead-free all-inorganic perovskite solar cells would offer a roadmap for developing new materials and navigate uncharted territory in solar energy fields.

DOI 10.11648/j.am.20190804.13
Published in Advances in Materials ( Volume 8, Issue 4, December 2019 )
Page(s) 142-155
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Perovskite Solar Cell, Power Conversion Efficiency, n-i-p Junction, Tandem, Up/Down Conversion, Intermediate Band

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    Liqiu Zheng, Robert S. Owor, Zhongrui Li. (2019). Environmentally Benign All-inorganic Perovskite Solar Cells. Advances in Materials, 8(4), 142-155. https://doi.org/10.11648/j.am.20190804.13

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    ACS Style

    Liqiu Zheng; Robert S. Owor; Zhongrui Li. Environmentally Benign All-inorganic Perovskite Solar Cells. Adv. Mater. 2019, 8(4), 142-155. doi: 10.11648/j.am.20190804.13

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    AMA Style

    Liqiu Zheng, Robert S. Owor, Zhongrui Li. Environmentally Benign All-inorganic Perovskite Solar Cells. Adv Mater. 2019;8(4):142-155. doi: 10.11648/j.am.20190804.13

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  • @article{10.11648/j.am.20190804.13,
      author = {Liqiu Zheng and Robert S. Owor and Zhongrui Li},
      title = {Environmentally Benign All-inorganic Perovskite Solar Cells},
      journal = {Advances in Materials},
      volume = {8},
      number = {4},
      pages = {142-155},
      doi = {10.11648/j.am.20190804.13},
      url = {https://doi.org/10.11648/j.am.20190804.13},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.am.20190804.13},
      abstract = {Organic/inorganic hybrid lead halide perovskite solar cells have recently emerged as the forerunner in the next generation of photovoltaic technology due to unprecedented progress in power conversion efficiency from their debut of 3.8% in 2009 to the currently certified 23.3%. Mixed PSC solar cells are subject to compositional degradation when exposed to ambient surroundings, which thwarts their real-world applications. Moreover, lead-based compounds pose environmental/health hazards. Very recently, all-inorganic lead-free perovskites have attracted enormous attention because this type successfully dismantles two roadblocks—instability and toxicity, which would accelerate the commercialization. In this outlook, we offered our perspective on the most recent developments in material sciences of halides all inorganic perovskites with possible alternatives to lead, the synthesis approaches, assessment of various device configurations and their progress in solar cells. For the sake of comparison, we also reviewed some all-inorganic but lead-based counterparts in order to motivate researchers to explore all the potentials. Surveying recent developments toward lead-free all-inorganic perovskite solar cells would offer a roadmap for developing new materials and navigate uncharted territory in solar energy fields.},
     year = {2019}
    }
    

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  • TY  - JOUR
    T1  - Environmentally Benign All-inorganic Perovskite Solar Cells
    AU  - Liqiu Zheng
    AU  - Robert S. Owor
    AU  - Zhongrui Li
    Y1  - 2019/10/14
    PY  - 2019
    N1  - https://doi.org/10.11648/j.am.20190804.13
    DO  - 10.11648/j.am.20190804.13
    T2  - Advances in Materials
    JF  - Advances in Materials
    JO  - Advances in Materials
    SP  - 142
    EP  - 155
    PB  - Science Publishing Group
    SN  - 2327-252X
    UR  - https://doi.org/10.11648/j.am.20190804.13
    AB  - Organic/inorganic hybrid lead halide perovskite solar cells have recently emerged as the forerunner in the next generation of photovoltaic technology due to unprecedented progress in power conversion efficiency from their debut of 3.8% in 2009 to the currently certified 23.3%. Mixed PSC solar cells are subject to compositional degradation when exposed to ambient surroundings, which thwarts their real-world applications. Moreover, lead-based compounds pose environmental/health hazards. Very recently, all-inorganic lead-free perovskites have attracted enormous attention because this type successfully dismantles two roadblocks—instability and toxicity, which would accelerate the commercialization. In this outlook, we offered our perspective on the most recent developments in material sciences of halides all inorganic perovskites with possible alternatives to lead, the synthesis approaches, assessment of various device configurations and their progress in solar cells. For the sake of comparison, we also reviewed some all-inorganic but lead-based counterparts in order to motivate researchers to explore all the potentials. Surveying recent developments toward lead-free all-inorganic perovskite solar cells would offer a roadmap for developing new materials and navigate uncharted territory in solar energy fields.
    VL  - 8
    IS  - 4
    ER  - 

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Author Information
  • Chemistry and Forensic Sciences Department, Albany State University, Albany, USA

  • Mathematics and Computer Sciences Department, Albany State University, Albany, USA

  • Electron Microbeam Analysis Laboratory, University of Michigan, Ann Arbor, USA

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