World Journal of Applied Chemistry

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Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media

Received: Aug. 27, 2019    Accepted: Sep. 19, 2019    Published: Oct. 09, 2019
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Abstract

The corrosion inhibition behaviour of Henna leaves on Tin in 1.0 M HCl and 1.0 M NaOH was investigated using weight loss technique at temperatures ranges, 25-50°C. The maximum inhibition efficiency was found to be 95.45 at optimum inhibitor concentration. The presence of the compound adsorbed on the tin coupons was verified by spectroscopic measurements of the surface before and after corrosion tests. The leaves extract of Lawsonia inermis was found to be more effective in alkaline solution. It also confirmed that the inhibition efficiency decreased with increased in temperature but increased with increasing inhibitor concentrations. The Activation energy, Gibbs free energy were found to be 28.131, 29.589 kJmol-1; -3.280, -3.245 kJmol-1 in acidic and alkaline media respectively. The adsorption was found to obey Freundlich isotherm with linear coefficient (R2) and equilibrium parameter Kads to be 0.972, 0.957; 0.06, 0.05 for both systems in acidic and alkaline media respectively. Physical adsorption mechanism is proposed from the trend of ∆Gads. The negative values of ∆Gads shows the spontaneity of the inhibition process. The increase in the activation energy of the inhibition processes with values of 80kJ/mol support the mechanism of physical adsorption process. Lawsonia inermis leaves extract has proved to be more excellent inhibitor for tin in NaOH alkaline.

DOI 10.11648/j.wjac.20190404.11
Published in World Journal of Applied Chemistry ( Volume 4, Issue 4, December 2019 )
Page(s) 45-51
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This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Corrosion, Henna, Tin, Acidic, Alkaline Solution

References
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[2] Raja PB, Sethuraman MG. Natural products as corrosion inhibitor for metals in corrosive media. Mater. Lett. 2008; Vol 62: pp 113-116.
[3] Raja PB, Sethuraman MG. Inhibitive effect of black pepper extract on the sulphuric acid corrosion of mild steel. Mater. Lett. 2008; Vol 62: pp 2977-2979.
[4] Raja PB, Sethuraman MG. Strychnos nux-vomica an eco-friendly corrosion inhibitor for mild steel in 1 M sulphuric acid medium. Mater. Corros. 2009; Vol 22: pp 22-28.
[5] Sangeetha M, Rajendran S, Muthumegala TS, Krishanaveni A. Green corrosion inhibitors-An Overview. Zastitamaterijala. 2011; Vol 5: pp 3-19.
[6] Farooqi HI, Quraishi MA, Saini PA. Natural compounds as corrosion inhibitors for mild steel in industrial cooling systems. European Federation of corrosion. 1997; Vol 1: pp 186-194.
[7] Mukherjee D, Berchman J, Rajsekkar A, Sundarsanan N, Mahalingam R, Maruthamuthu S, Thiruchelvam T, Karaikudi, D. Plant-based alkaloids inhibit corrosion of marine alloys. Anti-Corros Method Material. 1997; Vol 44: pp 186-194.
[8] Rajendran. S, Agasta. M., Devi. B. R, Devi. S. B, Rajam. k. and JEYASUNDARI (2009). Corrosion Inhibition by an Aqueous Extract of Henna Leaves (LawsoniaInermis L). Scientific paper UDC: 620.1934, Vol 20: pp 77-83.
[9] Hamdy. A. and Nour Sh. El-Gendy (2012). Thermodynamic, adsorption and electrochemical Studies for Corrosion inhibition of carbon Steel by Henna Extract in acid Medium. Egyptian Journal of Petroleum, Vol 1: pp 17-24.
[10] Al-Sehaibani. H (2000). Evaluation of Extraction of Henna leaves as Environmentally Friendly Corrosion Inhibitor for Metals. Materialwisson Schaftund work Stofftochnlk, Vol 31 (12): pp 1060-1063.
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[12] Nnanna L. A., Anozie I. U, Avoaja A. G. I., Akoma C. S. And Eti E. P (2011). Comparative Study of Corrosion Inhibition of Auminium Alloy of Type AA3003 in Acidic and Alkaline Media by Euphorbia Hirta Extract. African Journal of Pure and Applied Chemistry Vol. 5 (8): pp 265-271.
[13] Sharma. K. S (2012). Basics of Corrosion Chemistry. Published by Wiley-VCH Verlag GmbH and Co. KGaA, Vol 1: pp 1-6.
[14] James A. O. and Akaranta O., (2009). The Inhibition of Corrosion of Zinc in 2.0 M Hydrochloric acid Solution with Acetone Extract of red Onion Skin. African Journal of Pure and Applied Chemistry, Vol 3 (11): pp 212.
[15] Nwabanne, J. T. and Okafor, V. N., (2011). Inhibition of the Corrosion of Mild Steel in Acidic Medium by Vernonia Amygdalina: Adsorption and thermodynamics Study. Journal of Emerging Trends in Engineering and Applied Sciences, Vol 2 (4): pp 619-625.
[16] Ituen, E. B., Udo, U. E., Odozi, N. W. and Dan, E. U. (2013). Adsorption and Kinetic/Thermodynamic Characterization of Aluminium Corrosion Inhibition in Sulphuric Acid by Extract of Astoniaboonei. IOSR Journal of Applied Chemistry, Vol 3: pp 52-59.
[17] Rani, A. B. E. and Basu, J. B. B (2012). Green Inhibitors for Corrosion Protection of Metals and Alloys: An Overview. International Journal of Corrosion, Vol 1: pp 1-15.
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    Muhammad Bashir Ibrahim, Zakariyau Sulaiman, Bishir Usman, Muhammad Adamu Ibrahim. (2019). Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media. World Journal of Applied Chemistry, 4(4), 45-51. https://doi.org/10.11648/j.wjac.20190404.11

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    Muhammad Bashir Ibrahim; Zakariyau Sulaiman; Bishir Usman; Muhammad Adamu Ibrahim. Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media. World J. Appl. Chem. 2019, 4(4), 45-51. doi: 10.11648/j.wjac.20190404.11

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    AMA Style

    Muhammad Bashir Ibrahim, Zakariyau Sulaiman, Bishir Usman, Muhammad Adamu Ibrahim. Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media. World J Appl Chem. 2019;4(4):45-51. doi: 10.11648/j.wjac.20190404.11

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  • @article{10.11648/j.wjac.20190404.11,
      author = {Muhammad Bashir Ibrahim and Zakariyau Sulaiman and Bishir Usman and Muhammad Adamu Ibrahim},
      title = {Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media},
      journal = {World Journal of Applied Chemistry},
      volume = {4},
      number = {4},
      pages = {45-51},
      doi = {10.11648/j.wjac.20190404.11},
      url = {https://doi.org/10.11648/j.wjac.20190404.11},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.wjac.20190404.11},
      abstract = {The corrosion inhibition behaviour of Henna leaves on Tin in 1.0 M HCl and 1.0 M NaOH was investigated using weight loss technique at temperatures ranges, 25-50°C. The maximum inhibition efficiency was found to be 95.45 at optimum inhibitor concentration. The presence of the compound adsorbed on the tin coupons was verified by spectroscopic measurements of the surface before and after corrosion tests. The leaves extract of Lawsonia inermis was found to be more effective in alkaline solution. It also confirmed that the inhibition efficiency decreased with increased in temperature but increased with increasing inhibitor concentrations. The Activation energy, Gibbs free energy were found to be 28.131, 29.589 kJmol-1; -3.280, -3.245 kJmol-1 in acidic and alkaline media respectively. The adsorption was found to obey Freundlich isotherm with linear coefficient (R2) and equilibrium parameter Kads to be 0.972, 0.957; 0.06, 0.05 for both systems in acidic and alkaline media respectively. Physical adsorption mechanism is proposed from the trend of ∆Gads. The negative values of ∆Gads shows the spontaneity of the inhibition process. The increase in the activation energy of the inhibition processes with values of 80kJ/mol support the mechanism of physical adsorption process. Lawsonia inermis leaves extract has proved to be more excellent inhibitor for tin in NaOH alkaline.},
     year = {2019}
    }
    

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  • TY  - JOUR
    T1  - Effect of Henna Leaves on the Corrosion Inhibition of Tin in Acidic and Alkaline Media
    AU  - Muhammad Bashir Ibrahim
    AU  - Zakariyau Sulaiman
    AU  - Bishir Usman
    AU  - Muhammad Adamu Ibrahim
    Y1  - 2019/10/09
    PY  - 2019
    N1  - https://doi.org/10.11648/j.wjac.20190404.11
    DO  - 10.11648/j.wjac.20190404.11
    T2  - World Journal of Applied Chemistry
    JF  - World Journal of Applied Chemistry
    JO  - World Journal of Applied Chemistry
    SP  - 45
    EP  - 51
    PB  - Science Publishing Group
    SN  - 2637-5982
    UR  - https://doi.org/10.11648/j.wjac.20190404.11
    AB  - The corrosion inhibition behaviour of Henna leaves on Tin in 1.0 M HCl and 1.0 M NaOH was investigated using weight loss technique at temperatures ranges, 25-50°C. The maximum inhibition efficiency was found to be 95.45 at optimum inhibitor concentration. The presence of the compound adsorbed on the tin coupons was verified by spectroscopic measurements of the surface before and after corrosion tests. The leaves extract of Lawsonia inermis was found to be more effective in alkaline solution. It also confirmed that the inhibition efficiency decreased with increased in temperature but increased with increasing inhibitor concentrations. The Activation energy, Gibbs free energy were found to be 28.131, 29.589 kJmol-1; -3.280, -3.245 kJmol-1 in acidic and alkaline media respectively. The adsorption was found to obey Freundlich isotherm with linear coefficient (R2) and equilibrium parameter Kads to be 0.972, 0.957; 0.06, 0.05 for both systems in acidic and alkaline media respectively. Physical adsorption mechanism is proposed from the trend of ∆Gads. The negative values of ∆Gads shows the spontaneity of the inhibition process. The increase in the activation energy of the inhibition processes with values of 80kJ/mol support the mechanism of physical adsorption process. Lawsonia inermis leaves extract has proved to be more excellent inhibitor for tin in NaOH alkaline.
    VL  - 4
    IS  - 4
    ER  - 

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Author Information
  • Department of Pure and Industrial Chemistry, Bayero University, Kano, Nigeria

  • Department of Pure and Industrial Chemistry, Bayero University, Kano, Nigeria

  • Department of Pure and Industrial Chemistry, Bayero University, Kano, Nigeria

  • Department of Pure and Industrial Chemistry, Bayero University, Kano, Nigeria

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