This research studies the effect of several toughening agents, such as carboxyl-terminated polyether (CTPE), carboxyl-terminated polytetrahydrofuran (CTPF), carboxyl-terminated liquid nitrile rubber (CTBN), random-base liquid nitrile-butadiene rubber (RBNR) and core-shell polymer (CSP) containing polybutadiene, on epoxy resin. These epoxy resin systems containing various toughening agents showed different viscosity, in which the viscosity of CTPE and CTPF systems nearly unchanged and the viscosity of CTBN, RNBR and CSP systems increased significantly. The impact resistance of modified epoxy systems had been improved significantly, especially the CTPF system raised by 257.2%. Meanwhile, the heat resistance of epoxy systems containing different toughening agents showed different results. Compared with the pure sample, the hardness of all toughened systems decreased. CTPE and CTBN systems decreased significantly, while CTPF and CSP remained fundamentally unchanged. Toughness modification resulted in reduction of tensile strength and the retention ratio was CSP > RNBR > CTPF > CTBN > CTPE. Toughness modification resulted in reduction of compression strength and the retention ratio was RNBR > CSP > CTPF > CTBN > CTPE. All of the toughening systems kept the shear strength basically unchanged. The shear strength of the CSP system was even improved. In terms of peel strength, all of toughening systems had improved.
| DOI | 10.11648/j.ijimse.20190402.11 |
| Published in |
International Journal of Industrial and Manufacturing Systems Engineering (Volume 4, Issue 2, March 2019)
This article belongs to the Special Issue Manufacturing Strategy for Competitiveness |
| Page(s) | 19-23 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Epoxy Resin, Toughening, CTPE, CTPF, CTBN, RBNR, CSP
| [1] | Zhao, X. W.; Zang, C. G.; Wen, Y. Q.; Jiao, Q. J. J. J. o. A. S.; Technology, Studies on adhesion performance of addition-curable liquid silicone rubber on epoxy networks treated with different structures borosiloxane oligomers. 2019, 33 (8), 1-10. |
| [2] | Zhao, X.; Zang, C.; Sun, Y.; Liu, K.; Wen, Y.; Jiao, Q. J. J. o. M. S., Borosiloxane oligomers for improving adhesion of addition-curable liquid silicone rubber with epoxy resin by surface treatment. 2018, 53 (2), 1167-1177. |
| [3] | Gao, L.; Wang, J. J. J. o. A. P. S., Thermal, mechanical, and dielectric studies on the DGEBA epoxy blends by using liquid oxidized poly (1, 2‐butadiene) as a reactive component. 2017, 134 (15). |
| [4] | Vertuccio, L.; Guadagno, L.; Spinelli, G.; Russo, S.; Iannuzzo, G. J. C. P. B. E., Effect of carbon nanotube and functionalized liquid rubber on mechanical and electrical properties of epoxy adhesives for aircraft structures. 2017, 129. |
| [5] | Fauzi, F. S.; Teh, P. L.; Du, N. U. L.; Yeoh, C. K. J. M. S. F., The Effect of Liquid Natural Rubber as Toughening Agent in Epoxy/LNR/CB Composite. 2017, 888, 216-221. |
| [6] | Nishida, H.; Carvelli, V.; Fujii, T.; Okubo, K. J. C. P. B. E., Quasi-static and fatigue performance of carbon fibre reinforced highly polymerized thermoplastic epoxy. 2018, 144, 163-170. |
| [7] | Bakar, M.; Białkowska, A.; Kuřitka, I.; Hanuliková, B.; Masař, M. J. P. C., Synergistic effects of thermoplastic and nanoclay on the performance properties and morphology of epoxy resin. 2018, 39 (S4). |
| [8] | Guo, S.; Kang, Z.; Feng, Z.; Hou, Y.; Hao, L.; Jing, Z.; Tian, Y.; Song, H. J. A. S. S., High Performance Liquid Crystalline Bionanocomposite Ionogels Prepared by In Situ Crosslinking of Cellulose/Halloysite Nanotubes/Ionic Liquid Dispersions and Its Application in Supercapacitors. 2018, 455, 599-607. |
| [9] | Dwulet, G. E.; Gin, D. L. J. C. C., Ordered nanoporous lyotropic liquid crystal polymer resin for heterogeneous catalytic aerobic oxidation of alcohols. 2018, 54 (2–3). |
| [10] | Quan, D.; Ivankovic, A. J. P., Effect of core–shell rubber (CSR) nano-particles on mechanical properties and fracture toughness of an epoxy polymer. 2015, 66, 16-28. |
| [11] | Thitsartarn, W.; Fan, X.; Yang, S.; Yeo, J. C. C.; Yuan, D.; He, C. J. C. S.; Technology, Simultaneous enhancement of strength and toughness of epoxy using POSS-Rubber core–shell nanoparticles. 2015, 118, 63-71. |
| [12] | Hashemi, S. A.; Mousavi, S. M.; Faghihi, R.; Arjmand, M.; Sina, S.; Amani, A. M. J. R. P.; Chemistry, Lead Oxide-Decoratiod Graphene Oxide/Epoxy Composite towards X-Ray Radiation Shielding. 2018, 146, S0969806X17307089. |
| [13] | Jin, T.; Han, Y.; Bai, R.; Liu, X. J. J. o. N.; Nanotechnology, Corrosion Protection Properties of Nano NH2-Reduced Graphene Oxide/Epoxy Composite Coatings Formed by Self-Curing on Magnesium Alloy. 2018, 18 (7), 4971. |
| [14] | Vryonis, O.; Virtanen, S. T. H.; Andritsch, T.; Vaughan, A. S.; Lewin, P. L. J. J. o. M. S., Understanding the cross-linking reactions in highly oxidized graphene/epoxy nanocomposite systems. 2019. |
| [15] | Thomas, S.; Jankowski, E. J. J. o. T.; Chemistry, C., Routine million-particle simulations of epoxy curing with dissipative particle dynamics. 2018, S0219633618400059. |
| [16] | Ragunath, S.; Velmurugan, C.; Kannan, T. J. P. f. A. T., Optimization of tribological behavior of nano clay particle with sisal/jute/glass/epoxy polymer hybrid composites using RSM. 2017, (3). |
| [17] | Xiao, C.; Tan, Y.; Yang, X.; Xu, T.; Wang, L.; Qi, Z. J. C. P. L., Mechanical properties and strengthening mechanism of epoxy resin reinforced with nano-SiO 2 particles and multi-walled carbon nanotubes. 2018, 695. |
| [18] | Huang, Y.; Tian, Y.; Li, Y.; Tan, X.; Li, Q.; Cheng, J.; Zhang, J., High mechanical properties of epoxy networks with dangling chains and tunable microphase separation structure. RSC Adv. 2017, 7 (77), 49074-49082. |
| [19] | Ba, L.; Zou, Q.; Tan, X.; Song, J.; Cheng, J.; Zhang, J., Structure, morphology and properties of epoxy networks with dangling chains cured by anhydride. RSC Advances 2016, 6 (94), 91875-91881. |
APA Style
Zhou Jianwen, Huang Yizhou, Wang Hong, Huang Yi. (2019). Practical Technology of Toughening Epoxy Resin: Influence of Toughening Agents on Mechanical and Heat Properties. International Journal of Industrial and Manufacturing Systems Engineering, 4(2), 19-23. https://doi.org/10.11648/j.ijimse.20190402.11
ACS Style
Zhou Jianwen; Huang Yizhou; Wang Hong; Huang Yi. Practical Technology of Toughening Epoxy Resin: Influence of Toughening Agents on Mechanical and Heat Properties. Int. J. Ind. Manuf. Syst. Eng. 2019, 4(2), 19-23. doi: 10.11648/j.ijimse.20190402.11
AMA Style
Zhou Jianwen, Huang Yizhou, Wang Hong, Huang Yi. Practical Technology of Toughening Epoxy Resin: Influence of Toughening Agents on Mechanical and Heat Properties. Int J Ind Manuf Syst Eng. 2019;4(2):19-23. doi: 10.11648/j.ijimse.20190402.11
Share This Article
Twitter
Linked In
Facebook
Copy
Download@article{10.11648/j.ijimse.20190402.11,
author = {Zhou Jianwen and Huang Yizhou and Wang Hong and Huang Yi},
title = {Practical Technology of Toughening Epoxy Resin: Influence of Toughening Agents on Mechanical and Heat Properties},
journal = {International Journal of Industrial and Manufacturing Systems Engineering},
volume = {4},
number = {2},
pages = {19-23},
doi = {10.11648/j.ijimse.20190402.11},
url = {https://doi.org/10.11648/j.ijimse.20190402.11},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijimse.20190402.11},
abstract = {This research studies the effect of several toughening agents, such as carboxyl-terminated polyether (CTPE), carboxyl-terminated polytetrahydrofuran (CTPF), carboxyl-terminated liquid nitrile rubber (CTBN), random-base liquid nitrile-butadiene rubber (RBNR) and core-shell polymer (CSP) containing polybutadiene, on epoxy resin. These epoxy resin systems containing various toughening agents showed different viscosity, in which the viscosity of CTPE and CTPF systems nearly unchanged and the viscosity of CTBN, RNBR and CSP systems increased significantly. The impact resistance of modified epoxy systems had been improved significantly, especially the CTPF system raised by 257.2%. Meanwhile, the heat resistance of epoxy systems containing different toughening agents showed different results. Compared with the pure sample, the hardness of all toughened systems decreased. CTPE and CTBN systems decreased significantly, while CTPF and CSP remained fundamentally unchanged. Toughness modification resulted in reduction of tensile strength and the retention ratio was CSP > RNBR > CTPF > CTBN > CTPE. Toughness modification resulted in reduction of compression strength and the retention ratio was RNBR > CSP > CTPF > CTBN > CTPE. All of the toughening systems kept the shear strength basically unchanged. The shear strength of the CSP system was even improved. In terms of peel strength, all of toughening systems had improved.},
year = {2019}
}
TY - JOUR T1 - Practical Technology of Toughening Epoxy Resin: Influence of Toughening Agents on Mechanical and Heat Properties AU - Zhou Jianwen AU - Huang Yizhou AU - Wang Hong AU - Huang Yi Y1 - 2019/10/24 PY - 2019 N1 - https://doi.org/10.11648/j.ijimse.20190402.11 DO - 10.11648/j.ijimse.20190402.11 T2 - International Journal of Industrial and Manufacturing Systems Engineering JF - International Journal of Industrial and Manufacturing Systems Engineering JO - International Journal of Industrial and Manufacturing Systems Engineering SP - 19 EP - 23 PB - Science Publishing Group SN - 2575-3142 UR - https://doi.org/10.11648/j.ijimse.20190402.11 AB - This research studies the effect of several toughening agents, such as carboxyl-terminated polyether (CTPE), carboxyl-terminated polytetrahydrofuran (CTPF), carboxyl-terminated liquid nitrile rubber (CTBN), random-base liquid nitrile-butadiene rubber (RBNR) and core-shell polymer (CSP) containing polybutadiene, on epoxy resin. These epoxy resin systems containing various toughening agents showed different viscosity, in which the viscosity of CTPE and CTPF systems nearly unchanged and the viscosity of CTBN, RNBR and CSP systems increased significantly. The impact resistance of modified epoxy systems had been improved significantly, especially the CTPF system raised by 257.2%. Meanwhile, the heat resistance of epoxy systems containing different toughening agents showed different results. Compared with the pure sample, the hardness of all toughened systems decreased. CTPE and CTBN systems decreased significantly, while CTPF and CSP remained fundamentally unchanged. Toughness modification resulted in reduction of tensile strength and the retention ratio was CSP > RNBR > CTPF > CTBN > CTPE. Toughness modification resulted in reduction of compression strength and the retention ratio was RNBR > CSP > CTPF > CTBN > CTPE. All of the toughening systems kept the shear strength basically unchanged. The shear strength of the CSP system was even improved. In terms of peel strength, all of toughening systems had improved. VL - 4 IS - 2 ER -
Information
Email: