Colloid and Surface Science

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Bulk-Solution Properties of CpyCl/CTABr a Mixed Surfactant System in the Presence of Nonionic Hydrotropes

Received: Apr. 27, 2018    Accepted: May 31, 2018    Published: Sep. 13, 2018
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Abstract

The current research work centred on the micellization of binary system of Cetylpyridinium chloride (CpyCl) and cetyltrimethylammonium bromide (CTABr) in the absence and presence of nonionic hydrotropes (i.e urea and resorcinol) using conductometric technique. The critical micelle concentrations (CMC), at different mixed mole fraction of mixed surfactant were evaluated. Activity coefficient, ideal CMC, micellar mole fraction, interaction and thermodynamic parameters were obtained using theoretical Clint and Rubingh models.Addition of hydrotropes lowered the CMC values than the ideal CMC values and the individual components which is an indication of positive synergistic interaction in CpyCl/CTABr mixed micelle formation. The interaction parameter values were all negative, signifying strong interaction between the mixed surfactant. The evaluated thermodynamic parameters were all negative, indicating spontaneity and stability of the mixed micelle formed.

DOI 10.11648/j.css.20180302.11
Published in Colloid and Surface Science ( Volume 3, Issue 2, June 2018 )
Page(s) 12-21
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Cetylpridinium Chloride, Mixed Micelle, Hydrotrope, Cetyltrimethylammonium Bromide, Thermodynamic Parameter, Resorcinol

References
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  • APA Style

    Olaseni Segun Esan, Bankole Owolabi Mutolib, Aboluwoye Christopher Olumuyiwa, Owoyomi Olarenwaju, Oyeneyin Oluwatoba Emmanuel. (2018). Bulk-Solution Properties of CpyCl/CTABr a Mixed Surfactant System in the Presence of Nonionic Hydrotropes. Colloid and Surface Science, 3(2), 12-21. https://doi.org/10.11648/j.css.20180302.11

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    ACS Style

    Olaseni Segun Esan; Bankole Owolabi Mutolib; Aboluwoye Christopher Olumuyiwa; Owoyomi Olarenwaju; Oyeneyin Oluwatoba Emmanuel. Bulk-Solution Properties of CpyCl/CTABr a Mixed Surfactant System in the Presence of Nonionic Hydrotropes. Colloid Surf. Sci. 2018, 3(2), 12-21. doi: 10.11648/j.css.20180302.11

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    AMA Style

    Olaseni Segun Esan, Bankole Owolabi Mutolib, Aboluwoye Christopher Olumuyiwa, Owoyomi Olarenwaju, Oyeneyin Oluwatoba Emmanuel. Bulk-Solution Properties of CpyCl/CTABr a Mixed Surfactant System in the Presence of Nonionic Hydrotropes. Colloid Surf Sci. 2018;3(2):12-21. doi: 10.11648/j.css.20180302.11

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  • @article{10.11648/j.css.20180302.11,
      author = {Olaseni Segun Esan and Bankole Owolabi Mutolib and Aboluwoye Christopher Olumuyiwa and Owoyomi Olarenwaju and Oyeneyin Oluwatoba Emmanuel},
      title = {Bulk-Solution Properties of CpyCl/CTABr a Mixed Surfactant System in the Presence of Nonionic Hydrotropes},
      journal = {Colloid and Surface Science},
      volume = {3},
      number = {2},
      pages = {12-21},
      doi = {10.11648/j.css.20180302.11},
      url = {https://doi.org/10.11648/j.css.20180302.11},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.css.20180302.11},
      abstract = {The current research work centred on the micellization of binary system of Cetylpyridinium chloride (CpyCl) and cetyltrimethylammonium bromide (CTABr) in the absence and presence of nonionic hydrotropes (i.e urea and resorcinol) using conductometric technique. The critical micelle concentrations (CMC), at different mixed mole fraction of mixed surfactant were evaluated. Activity coefficient, ideal CMC, micellar mole fraction, interaction and thermodynamic parameters were obtained using theoretical Clint and Rubingh models.Addition of hydrotropes lowered the CMC values than the ideal CMC values and the individual components which is an indication of positive synergistic interaction in CpyCl/CTABr mixed micelle formation. The interaction parameter values were all negative, signifying strong interaction between the mixed surfactant. The evaluated thermodynamic parameters were all negative, indicating spontaneity and stability of the mixed micelle formed.},
     year = {2018}
    }
    

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  • TY  - JOUR
    T1  - Bulk-Solution Properties of CpyCl/CTABr a Mixed Surfactant System in the Presence of Nonionic Hydrotropes
    AU  - Olaseni Segun Esan
    AU  - Bankole Owolabi Mutolib
    AU  - Aboluwoye Christopher Olumuyiwa
    AU  - Owoyomi Olarenwaju
    AU  - Oyeneyin Oluwatoba Emmanuel
    Y1  - 2018/09/13
    PY  - 2018
    N1  - https://doi.org/10.11648/j.css.20180302.11
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    T2  - Colloid and Surface Science
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    JO  - Colloid and Surface Science
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    EP  - 21
    PB  - Science Publishing Group
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    UR  - https://doi.org/10.11648/j.css.20180302.11
    AB  - The current research work centred on the micellization of binary system of Cetylpyridinium chloride (CpyCl) and cetyltrimethylammonium bromide (CTABr) in the absence and presence of nonionic hydrotropes (i.e urea and resorcinol) using conductometric technique. The critical micelle concentrations (CMC), at different mixed mole fraction of mixed surfactant were evaluated. Activity coefficient, ideal CMC, micellar mole fraction, interaction and thermodynamic parameters were obtained using theoretical Clint and Rubingh models.Addition of hydrotropes lowered the CMC values than the ideal CMC values and the individual components which is an indication of positive synergistic interaction in CpyCl/CTABr mixed micelle formation. The interaction parameter values were all negative, signifying strong interaction between the mixed surfactant. The evaluated thermodynamic parameters were all negative, indicating spontaneity and stability of the mixed micelle formed.
    VL  - 3
    IS  - 2
    ER  - 

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Author Information
  • Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Nigeria

  • Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Nigeria

  • Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Nigeria

  • Department of Chemistry, Obafemi Awolowo University, Ile-Ife, Nigeria

  • Department of Chemical Sciences, Adekunle Ajasin University, Akungba-Akoko, Nigeria

  • Section